Primary receptacles must be further packed in non-specification bulk outer packagings such as cubic yard boxes, plastic rigid-wall bulk containers, dump trailers, and roll-off containers. On the basis of the results of suitable burning rate tests, and taking into account the standard tests in the UN Manual of Tests and Criteria, Part III, subsection 33.2.1 (IBR, see 171.7 of this subchapter), nitrocellulose membrane filters in the form in which they are to be transported that do not meet the criteria for a Division 4.1 material are not subject to the requirements of this subchapter. Only Specifications MC 304, MC 307 or DOT 407 cargo tank motor vehicles are authorized for transportation by vessel. N45 Copper cartridges are authorized as inner packagings if the hazardous material is not in dispersion. The inlet to the venting device must be located in the vapor space of the IBC under maximum filling conditions. b. Using the nominal capacitance (CN), rated voltage (UR) and the rated lower limit voltage (UL). (b) Description of codes for special provisions. (6) The rate of oxygen release from the outer packaging does not exceed 15 mL per hour. N42 1A1 drums made of carbon steel with thickness of body and heads of not less than 1.3 mm (0.050 inch) and with a corrosion-resistant phenolic lining are authorized for stabilized benzyl chloride if tested and certified to the Packing Group I performance level at a specific gravity of not less than 1.8. If a tank car tank is equipped with a reclosing pressure relief valve, the tank must also be equipped with a vacuum relief valve. Portable tank instructions T1 through T22 specify the applicable minimum test pressure, the minimum shell thickness (in reference steel), bottom opening requirements and pressure relief requirements. Column 1 specifies the T Code. Lead compounds which, when mixed in a ratio of 1:1,000 with 0.07 M (Molar concentration) hydrochloric acid and stirred for one hour at a temperature of 23 C 2 C, exhibit a solubility of 5% or less are not subject to the requirements of this subchapter unless they meet criteria as another hazard class or division. For single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. 102 The ends of the detonating cord must be tied fast so that the explosive cannot escape. TP9 A hazardous material assigned to special provision TP9 in Column (7) of the 172.101 Table may only be transported in a portable tank if approved by the Associate Administrator. A14 This material is not authorized to be transported as a limited quantity or consumer commodity in accordance with 173.306 of this subchapter when transported aboard an aircraft. When a special provision specifies packaging or packaging requirements - A lighter refill exceeding 4 fluid ounces capacity (7.22 cubic inches) or containing more than 65 grams of fuel must be classed as a Division 2.1 material, described with the proper shipping name appropriate for the material, and packaged in the packaging specified in part 173 of this subchapter for the flammable gas contained therein. (c) Tables of special provisions. While columns 8 and 7 of the Hazardous Materials Table are used to determine authorized packaging for most HazMat (more on that in a little bit), some methods of transportation, HazMat quantities, and specific operations rely on other methods. It must not be used for machinery or apparatus for which a proper shipping name already exists in the 172.101 Table. If a frangible disc is required in series with the reclosing pressure relief device for the specified portable tank, the alternative portable tank must be fitted with a frangible disc in series with the reclosing pressure relief device; and, (1) When two effective means are specified, the alternative portable tank is fitted with bottom openings having two or three effective means of closure or no bottom openings; or, (2) When three effective means are specified, the portable tank has no bottom openings or three effective means of closure; or. citations and headings N34 Aluminum construction materials are not authorized for any part of a packaging which is normally in contact with the hazardous material. Use the navigation links in the gray bar above to view the table of contents that this content belongs to. Alternatively, the item itself may be used as a packaging if it meets the general packaging requirements of subparts A and B of part 173 of this subchapter. The packing group assignment and packaging must be approved by the Associate Administrator for Hazardous Materials Safety on the basis of the criteria in 173.21 of this subchapter and the package type used for the Series 6(c) test. Energy storage capacity means the energy stored in a capacitor, as calculated according to the following equation. 8 A hazardous substance that is not a hazardous waste may be shipped under the shipping description Other regulated substances, liquid or solid, n.o.s., as appropriate. When there is an entry in this column, refer to Section 172.102 of the federal regulations for specific information. These provisions apply only to transportation by water: W1 This substance in a non friable prill or granule form is not subject to the requirements of this subchapter when tested in accordance with the UN Manual of Test and Criteria (IBR, see 171.7 of this subchapter) and is found to not meet the definition or criteria for inclusion in Division 5.1. c. Every installed inflation cylinder, as associated equipment of the life-saving appliance, must be packed within the protective packaging of the life raft and the life raft itself must otherwise be in compliance with 173.219. d. The serial number for each cylinder must be recorded as part of the life-saving appliance service record by the U.S. Coast Guard-approved servicing facility. B131 When transported by highway, rail, or cargo vessel, waste Paint and Paint related material (UN1263; PG II and PG III), when in plastic or metal inner packagings of not more than 26.5 L (7 gallons), are excepted from the marking requirements in 172.301(a) and (c) and the labeling requirements in 172.400(a), when further packed in the following specification and non-specification bulk outer packagings and under the following conditions: a. These entries include hybrid electric vehicles powered by a fuel cell engine, an internal combustion engine, and batteries. (iii) A copy of the test results must be kept on file at each facility where packagings are offered for transportation, and must be made available to a representative of the Department upon request. In addition, there are over 300 numeric codes provisions. Interior heating coils are not authorized. the hierarchy of the document. Mixtures containing at least 98%, by mass, of phlegmatizer are not subject to the requirements of this subchapter. 44 The formulation must be prepared so that it remains homogenous and does not separate during transport. This web site is designed for the current versions of Column 7: Special Provisions - Specifies codes for special provisions applicable to some hazardous materials. 61 A chemical oxygen generator is spent if its means of ignition and all or a part of its chemical contents have been expended. (7) Special Provisions (172.102) IB8, IP2, IP4 iv. b. Navigate by entering citations or phrases Portable tanks must be hydraulically tested and internally inspected at intervals not exceeding 2.5 years. shipping name in Column (1) of the 172.101 Table, it means that the mate-rial is known to pose a risk to humans. 365 For manufactured instruments and articles containing mercury, see UN3506. Each tank car must have a reclosing pressure relief device having a start-to-discharge pressure of 10.34 Bar (150 psig). guide. Packagings of other material with a small amount of metal, for example metal closures or other metal fittings such as those mentioned in part 178 of this subchapter, are not considered metal packagings. Additionally, unless otherwise excepted in this subchapter, polyester resin kits must be packaged in specification combination packagings based on the performance level of the base material contained within the kit. N95 UN1075, Liquefied petroleum gas and UN1978, Propane authorized for transport in DOT 4BA240 cylinders is not subject to the UN identification number and proper shipping name marking or the label requirements of this part subject to the following conditions: a. Energy storage capacity means the energy held by a capacitor, as calculated using the nominal voltage and capacitance. e. When offered for transport in an ammonia dispenser, the receptacles shall be connected to the dispenser in such a way that the assembly is guaranteed to have the same strength as a single receptacle. No Class 7 label is required to be displayed. N6 Battery fluid packaged with electric storage batteries, wet or dry, must conform to the packaging provisions of 173.159 (g) or (h) of this subchapter. Each transport unit must be leakproof when used as bulk packaging. The manufacturer must apply procedures to ensure that articles produced in series are made of good quality, conform to the design type and are able to meet the requirements in (a). Comments or questions about document content can not be answered by OFR staff. The present arrangement occurs in such a way that one QA molecule is hydrogen-bonded to four neighboring molecules: two different molecules in one column and other two molecules in another column. contact the publishing agency. N32 Aluminum materials of construction are not authorized for single packagings. The cargo transport unit shall display the UN number in a manner in accordance with 172.332 of this subchapter and be placarded on two opposing sides. When used for purposes such as sterilization, inner packagings of peroxyacetic acid, stabilized, classified as UN 3107 Organic peroxide type E, liquid or UN 3109 Organic peroxide type F, liquid may be fitted with a vent consisting of hydrophobic membrane, provided: (1) Each inner packaging contains not more than 70 mL; (2) The inner packaging is designed so that the vent is not immersed in liquid in any orientation; (3) Each inner packaging is enclosed in an intermediate rigid plastic packaging with a small opening to permit release of gas and contains a buffer that neutralizes the contents of the inner packaging in the event of leakage; (4) Intermediate packagings are packed in a fiberboard box (4G) outer packaging; (5) Each outer packaging contains not more than 1.4 L of liquid; and. The coal tar pitch compound must be in a solid mass during transportation. (3) A flammable gas is a gas that meets the criteria in 173.115 of this subchapter. However, the design stress limits may not exceed 25 percent of the stress for 0 temper at the maximum design temperature of the cargo tank, as specified in the Aluminum Association's Aluminum Standards and Data (IBR, see 171.7 of this subchapter). Model rocket motors containing 30 grams or less propellant are classed as Division 1.4S and items containing more than 30 grams of propellant but not more than 62.5 grams of propellant are classed as Division 1.4C. Company Name: Artisan EHS Consulting, LLC. (vi) Except when an organic peroxide is authorized under 173.225(g), if a hazardous material is not assigned a portable tank T Code, the hazardous material may not be transported in a portable tank unless approved by the Associate Administrator. Pressure relief devices shall be designed to prevent the entry of foreign matter, the leakage of liquid and the development of any dangerous excess pressure. Except as provided in 173.185(c)(3) of this subchapter, the package must be marked UN 3091 Lithium metal batteries packed with equipment, or UN 3481 Lithium ion batteries packed with equipment, as appropriate. There must be no hazardous effects outside the package such as disruption of the package, metal fragments or a receptacle which passes through the packaging. Nickel-metal hydride button cells or nickel-metal hydride cells or batteries packed with or contained in battery-powered devices transported by vessel are not subject to the requirements of this special provision. No label is needed where the table shows the word NONE. 421 This entry will no longer be effective on January 2, 2023, unless we terminate it earlier or extend it beyond that date by notice of a final rule in the Federal Register. When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle. When phlegmatized with water and inorganic inert material, the content of urea nitrate must not exceed 75 percent by mass and the mixture should not be capable of being detonated by test 1(a)(i) or test 1(a)(ii) in the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). b. is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius. Data collection and handling. This entry applies to machinery or apparatus containing hazardous materials as a residue or as an integral element of the machinery or apparatus. N8 Nitroglycerin solution in alcohol may be transported under this entry only when the solution is packed in metal cans of not more than 1 L capacity each, overpacked in a wooden box containing not more than 5 L. Metal cans must be completely surrounded with absorbent cushioning material. b. For single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. For criteria in determining what is a new lighter design, see 173.308(b)(1). B130 When transported by motor vehicle, used diatomaceous earth filter material is not subject to any other requirements of this subchapter except for the shipping paper requirements of subpart C of part 172 of this subchapter; emergency response information as required by 172.602(a)(2) through (a)(7) of this subchapter; and the marking requirements of 172.302 of this subchapter, if the following requirements are met: a. Packagings are non-DOT specification sift-proof motor vehicles or sift-proof roll-on/roll-off bulk bins, which are covered by a tarpaulin or other equivalent means. c. The time between offering the material for transportation at the point of origin, and unloading the material at the destination does not exceed 48 hours. The official, published CFR, is updated annually and available below under Limited propagation means that if one booster near the center of the package is exploded, the aggregate weight of explosives, excluding ignition and delay charges, in this and all additional boosters in the outside packaging that explode may not exceed 25 g. 116 Fuzes, detonating may be classed in Division 1.4 if the fuzes do not contain more than 25 g of explosive per fuze and are made and packaged so that they will not cause functioning of other fuzes, explosives or other explosive devices if one of the fuzes detonates in a shipping packaging or in adjacent packages. Retain a copy of each notification of pilot-in-command if requested for up to 30 days Which one of the following hazardous materials is NOT excepted from the quantity limitations in 175.75? Openings for safety relief devices on multi-unit tank car tanks shall be plugged or blank flanged. If it is evident that a package of radioactive material, or conveyance carrying unpackaged radioactive material, is leaking, or if it is suspected that the package, or conveyance carrying unpackaged material, may have leaked, the requirements of 173.443(e) of this subchapter apply. The material may only be loaded with Class 3, Class 8, and Division 4.1 materials in Packing Group II or III. (See 173.50 of this subchapter.). A separate drafting site These special provisions are in addition to the standard packaging requirements. For all modes of transportation, a written report submitted, retained, and updated in accordance with 171.16 is required if a fire, violent rupture, explosion or dangerous evolution of heat occurs as a direct result of a dry battery or battery-powered device. The total weight of the explosive contents of the shaped charges assembled in the guns does not exceed 90.5 kg (200 pounds) per vehicle; and. The map below, compiled from data provided by the Federal Emergency Management Agency (FEMA), is the most accurate nuclear attack map and fallout demonstration available for 2023: (Image courtesy of FEMA and Halcyon Maps) The fallout would rapidly spread, turning targeted cities into whole affected regions. Flexible IBCs must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner. Non-specification bulk bins are authorized. Subpart BTable of Hazardous Materials and Special Provisions 172.101 Purpose and use of haz-ardous materials table. TP26 The heating device must be exterior to the shell. The maximum degree of filling must not exceed the degree of filling determined by the following: tr is the maximum mean bulk temperature during transport, tf is the temperature in degrees celsius of the liquid during filling, and. B46 The detachable protective housing for the loading and unloading valves of multi-unit tank car tanks must withstand tank test pressure and must be approved by the Associate Administrator. Effective January 1, 2014, for transportation domestically by highway or rail, this entry may only be used if the results of Test Series 6(d) of Part I of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) have demonstrated that any hazardous effects from accidental functioning are confined to within the package. Refrigerated liquefied gases that are authorized to be transported in portable tanks are specified in tank instruction T75. TP3 The maximum degree of filling (in %) for solids transported above their melting points and for elevated temperature liquids shall be determined by the following: Where: df and dr are the mean densities of the liquid at the mean temperature of the liquid during filling and the maximum mean bulk temperature during transport respectively. N78 Packages consisting of inner glass, earthenware, or polyethylene or other nonfragile plastic bottles or jars not over 0.5 kg (1.1 pounds) capacity each, or metal cans not over five pounds capacity each, packed in outer wooden boxes, barrels or kegs, or fiberboard boxes are authorized and need not conform to the requirements of part 178 of this subchapter. - Other Regulations Relating to Transportation, - Pipeline and Hazardous Materials Safety Administration, Department of Transportation, - Hazardous Materials Table, Special Provisions, Hazardous Materials Communications, Emergency Response Information, Training Requirements, and Security Plans, - Table of Hazardous Materials and Special Provisions, https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-172/subpart-B/section-172.102. The components may be placed in the same outer packaging provided they will not interact dangerously in the event of leakage. TP29 A portable tank having a minimum test pressure of 1.5 bar (150.0 kPa) may be used provided the calculated test pressure is 1.5 bar or less based on the MAWP of the hazardous materials, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. (9) W codes. If the material has a flash point of less than 38 C (100 F), then the bulk packaging requirements of 173.242 of this subchapter are applicable. The receptacles must be constructed with glass double walls having the space between the walls vacuum insulated and each receptacle must be transported in an outer packaging with sufficient cushioning and absorbent materials to protect the receptacle from damage. W41 When offered for transportation by water, this material must be packaged in bales and be securely and tightly bound with rope, wire or similar means. B134 For Large Packagings offered for transport by vessel, flexible or fibre inner packagings shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-resistant liner. 12 In concentrations greater than 40 percent, this material has strong oxidizing properties and is capable of starting fires in contact with combustible materials. "Published Edition". (iv) The name or symbol of the bottle producer, and the month and year of manufacture, must be marked by embossing, ink-jet printing of permanent ink, or other permanent means on the face or bottom of each bottle, in letters and numbers at least 6 mm (0.2 inch) high. TP44 Each portable tank must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. 332 Magnesium nitrate hexahydrate is not subject to the requirements of this subchapter. The unintended errors are summarized below. Symbol Meaning Which is the correct column for hazardous materials? B18 Open steel hoppers or bins are authorized. 5 If this material meets the definition for a material poisonous by inhalation (see 171.8 of this subchapter), a shipping name must be selected which identifies the inhalation hazard, in Division 2.3 or Division 6.1, as appropriate. Component cells of the battery must be of a type proved to meet the respective testing requirements of the Manual of Tests and Criteria, part III, subsection 38.3 (IBR, see 171.7 of this subchapter). b. B115 Rail cars, highway trailers, roll-on/roll-off bins, or other non-specification bulk packagings are authorized. B42 Tank cars constructed before March 16, 2009, must have a test pressure of 34.47 Bar (500 psig) or greater and conform to Class 105J. Do not enter until vapors have dissipated. The driver of the transport vehicle and the consignee(s) must be trained not to enter the transport vehicle until the ammonia vapors have dissipated, and the emergency response information on the shipping paper must indicate that the vehicle contains ammonia vapors.